| dc.contributor.author | Parsons, Andrew T. | |
| dc.contributor.author | Buchwald, Stephen Leffler | |
| dc.date.accessioned | 2013-11-01T17:15:38Z | |
| dc.date.available | 2013-11-01T17:15:38Z | |
| dc.date.issued | 2011-08 | |
| dc.date.submitted | 2011-06 | |
| dc.identifier.issn | 14337851 | |
| dc.identifier.issn | 1521-3773 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/81948 | |
| dc.description.abstract | Activating the inactive: A copper-catalyzed allylic trifluoromethylation of unactivated terminal olefins proceeds under mild conditions to produce linear allylic trifluoromethylated products with high E/Z selectivity (see scheme). The reaction can be applied to a range of substrates bearing numerous functional groups. Furthermore, the reaction is scalable and amenable to a benchtop setup. | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (GM46059) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (Postdoctoral Fellowship F32GM093532) | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.) (Grant ACHE-9808061) | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.) (Grant DBI-9729592) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (Grant 1S10RR13886-01) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | Wiley Blackwell | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1002/anie.201104053 | en_US |
| dc.rights | Creative Commons Attribution-Noncommercial-Share Alike 3.0 | en_US |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc-sa/3.0/ | en_US |
| dc.source | PMC | en_US |
| dc.title | Copper-Catalyzed Trifluoromethylation of Unactivated Olefins | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Parsons, Andrew T., and Stephen L. Buchwald. “Copper-Catalyzed Trifluoromethylation of Unactivated Olefins.” Angewandte Chemie International Edition 50, no. 39 (September 19, 2011): 9120-9123. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Parsons, Andrew T. | en_US |
| dc.contributor.mitauthor | Buchwald, Stephen Leffler | en_US |
| dc.relation.journal | Angewandte Chemie International Edition | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Parsons, Andrew T.; Buchwald, Stephen L. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0003-3875-4775 | |
| mit.license | OPEN_ACCESS_POLICY | en_US |
| mit.metadata.status | Complete | |
