| dc.contributor.author | Li, Yang | |
| dc.contributor.author | Cao, Rui | |
| dc.contributor.author | Lippard, Stephen J. | |
| dc.date.accessioned | 2013-11-18T13:48:44Z | |
| dc.date.available | 2013-11-18T13:48:44Z | |
| dc.date.issued | 2011-08 | |
| dc.date.submitted | 2011-07 | |
| dc.identifier.issn | 1523-7060 | |
| dc.identifier.issn | 1523-7052 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/82153 | |
| dc.description.abstract | A novel triptycene-based ligand with a preorganized framework was designed to model carboxylate-bridged diiron active sites in bacterial multicomponent monooxygenase (BMM) hydroxylase enzymes. The synthesis of the bis(benzoxazole)-appended ligand L1 depicted was accomplished in 11 steps. Reaction of L1 with iron(II) triflate and a carboxylate source afforded the desired diiron(II) complex [Fe[subscript 2]L1(μ-OH)(μ-O[subscript 2]CAr[superscript Tol])(OTf)[subscript 2]]. | en_US |
| dc.description.sponsorship | National Institute of General Medical Sciences (U.S.) (Grant G032134) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/ol201882v | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | PMC | en_US |
| dc.title | Design and Synthesis of a Novel Triptycene-Based Ligand for Modeling Carboxylate-Bridged Diiron Enzyme Active Sites | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Li, Yang, Rui Cao, and Stephen J. Lippard. “Design and Synthesis of a Novel Triptycene-Based Ligand for Modeling Carboxylate-Bridged Diiron Enzyme Active Sites.” Organic Letters 13, no. 19 (October 7, 2011): 5052-5055. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Li, Yang | en_US |
| dc.contributor.mitauthor | Cao, Rui | en_US |
| dc.contributor.mitauthor | Lippard, Stephen J. | en_US |
| dc.relation.journal | Organic Letters | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Li, Yang; Cao, Rui; Lippard, Stephen J. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0002-2693-4982 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
