| dc.contributor.author | Movassaghi, Mohammad | |
| dc.contributor.author | Ahmad, Omar K. | |
| dc.contributor.author | Lathrop, Stephen | |
| dc.date.accessioned | 2013-11-18T20:18:53Z | |
| dc.date.available | 2013-11-18T20:18:53Z | |
| dc.date.issued | 2011-07 | |
| dc.date.submitted | 2011-06 | |
| dc.identifier.issn | 0002-7863 | |
| dc.identifier.issn | 1520-5126 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/82464 | |
| dc.description.abstract | A general strategy for the directed and stereocontrolled assembly of carbon–carbon linked heterodimeric hexahydropyrroloindoles is described. The stepwise union of complex amines in the form of mixed diazenes followed by photoexpulsion of dinitrogen in a solvent cage provides completely guided assembly at challenging C[3 over sp]–C[3 over sp] and C[3 over sp]–C[2 over sp] connections. | en_US |
| dc.description.sponsorship | National Institute of General Medical Sciences (U.S.) (GM089732) | en_US |
| dc.description.sponsorship | Amgen Inc. | en_US |
| dc.description.sponsorship | DuPont (Firm) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/ja2057852 | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | PMC | en_US |
| dc.title | Directed Heterodimerization: Stereocontrolled Assembly via Solvent-Caged Unsymmetrical Diazene Fragmentation | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Movassaghi, Mohammad, Omar K. Ahmad, and Stephen P. Lathrop. “Directed Heterodimerization: Stereocontrolled Assembly via Solvent-Caged Unsymmetrical Diazene Fragmentation.” Journal of the American Chemical Society 133, no. 33 (August 24, 2011): 13002-13005. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Movassaghi, Mohammad | en_US |
| dc.contributor.mitauthor | Ahmad, Omar K. | en_US |
| dc.contributor.mitauthor | Lathrop, Stephen | en_US |
| dc.relation.journal | Journal of the American Chemical Society | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Movassaghi, Mohammad; Ahmad, Omar K.; Lathrop, Stephen P. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0003-3080-1063 | |
| dspace.mitauthor.error | true | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
