| dc.contributor.author | Jui, Nathan T. | |
| dc.contributor.author | Buchwald, Stephen Leffler | |
| dc.date.accessioned | 2014-02-21T18:28:53Z | |
| dc.date.available | 2014-02-21T18:28:53Z | |
| dc.date.issued | 2013-10 | |
| dc.identifier.issn | 14337851 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/85069 | |
| dc.description.abstract | By choice: The palladium-catalyzed cascade reaction of 2-chloroaryl sulfonates with arylamine and amide nucleophiles provides direct access to N-arylbenzimidazoles. This strategy selectively produces the heterocycles based on chemoselective oxidative addition. 2-Chloroaryl triflates (Tf) produce one regioisomer and the corresponding 2-chloroaryl mesylates (Ms) deliver the other in a selectable manner. | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (GM58160) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (GM099817) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | John Wiley & Sons, Inc | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1002/anie.201306007 | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | Nathan T. Jui | en_US |
| dc.title | Cascade Palladium Catalysis: A Predictable and Selectable Regiocontrolled Synthesis of N-Arylbenzimidazoles | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Jui, Nathan T., and Stephen L. Buchwald. “Cascade Palladium Catalysis: A Predictable and Selectable Regiocontrolled Synthesis of N-Arylbenzimidazole.” Angewandte Chemie International Edition 52, no. 44 (October 25, 2013): 11624-11627. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Buchwald, Stephen Leffler | en_US |
| dc.relation.journal | Angewandte Chemie International Edition | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Jui, Nathan T.; Buchwald, Stephen L. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0003-3875-4775 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
