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dc.contributor.authorFors, Brett P.
dc.contributor.authorVinogradova, Ekaterina
dc.contributor.authorPark, Nathaniel Hamilton
dc.contributor.authorBuchwald, Stephen Leffler
dc.date.accessioned2015-02-06T19:29:27Z
dc.date.available2015-02-06T19:29:27Z
dc.date.issued2013-02
dc.date.submitted2013-02
dc.identifier.issn1523-7060
dc.identifier.issn1523-7052
dc.identifier.urihttp://hdl.handle.net/1721.1/93908
dc.description.abstractAn efficient synthesis of aryl carbamates was achieved by introducing alcohols into the reaction of palladium-catalyzed cross-coupling of ArX (X = Cl, OTf) with sodium cyanate. The use of aryl triflates as electrophilic components in this transformation allowed for an expanded substrate scope for direct synthesis of aryl isocyanates. This methodology provides direct access to major carbamate protecting groups, S-thiocarbamates, and diisocyanate precursors to polyurethane materials.en_US
dc.description.sponsorshipNational Institutes of Health (U.S.) (GM58160)en_US
dc.description.sponsorshipNational Science Foundation (U.S.). Graduate Research Fellowshipen_US
dc.language.isoen_US
dc.publisherAmerican Chemical Society (ACS)en_US
dc.relation.isversionofhttp://dx.doi.org/10.1021/ol400369nen_US
dc.rightsArticle is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.en_US
dc.sourcePMCen_US
dc.titlePalladium-Catalyzed Synthesis of N-Aryl Carbamatesen_US
dc.typeArticleen_US
dc.identifier.citationVinogradova, Ekaterina V., Nathaniel H. Park, Brett P. Fors, and Stephen L. Buchwald. “Palladium-Catalyzed Synthesis of N -Aryl Carbamates.” Org. Lett. 15, no. 6 (March 15, 2013): 1394–1397.en_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Chemistryen_US
dc.contributor.mitauthorVinogradova, Ekaterinaen_US
dc.contributor.mitauthorPark, Nathaniel Hamiltonen_US
dc.contributor.mitauthorFors, Brett P.en_US
dc.contributor.mitauthorBuchwald, Stephen Leffleren_US
dc.relation.journalOrganic Lettersen_US
dc.eprint.versionAuthor's final manuscripten_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/PeerRevieweden_US
dspace.orderedauthorsVinogradova, Ekaterina V.; Park, Nathaniel H.; Fors, Brett P.; Buchwald, Stephen L.en_US
dc.identifier.orcidhttps://orcid.org/0000-0002-3967-2483
dc.identifier.orcidhttps://orcid.org/0000-0003-3875-4775
mit.licensePUBLISHER_POLICYen_US


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