| dc.contributor.author | Fors, Brett P. | |
| dc.contributor.author | Vinogradova, Ekaterina | |
| dc.contributor.author | Park, Nathaniel Hamilton | |
| dc.contributor.author | Buchwald, Stephen Leffler | |
| dc.date.accessioned | 2015-02-06T19:29:27Z | |
| dc.date.available | 2015-02-06T19:29:27Z | |
| dc.date.issued | 2013-02 | |
| dc.date.submitted | 2013-02 | |
| dc.identifier.issn | 1523-7060 | |
| dc.identifier.issn | 1523-7052 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/93908 | |
| dc.description.abstract | An efficient synthesis of aryl carbamates was achieved by introducing alcohols into the reaction of palladium-catalyzed cross-coupling of ArX (X = Cl, OTf) with sodium cyanate. The use of aryl triflates as electrophilic components in this transformation allowed for an expanded substrate scope for direct synthesis of aryl isocyanates. This methodology provides direct access to major carbamate protecting groups, S-thiocarbamates, and diisocyanate precursors to polyurethane materials. | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (GM58160) | en_US |
| dc.description.sponsorship | National Science Foundation (U.S.). Graduate Research Fellowship | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/ol400369n | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | PMC | en_US |
| dc.title | Palladium-Catalyzed Synthesis of N-Aryl Carbamates | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Vinogradova, Ekaterina V., Nathaniel H. Park, Brett P. Fors, and Stephen L. Buchwald. “Palladium-Catalyzed Synthesis of N -Aryl Carbamates.” Org. Lett. 15, no. 6 (March 15, 2013): 1394–1397. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Vinogradova, Ekaterina | en_US |
| dc.contributor.mitauthor | Park, Nathaniel Hamilton | en_US |
| dc.contributor.mitauthor | Fors, Brett P. | en_US |
| dc.contributor.mitauthor | Buchwald, Stephen Leffler | en_US |
| dc.relation.journal | Organic Letters | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Vinogradova, Ekaterina V.; Park, Nathaniel H.; Fors, Brett P.; Buchwald, Stephen L. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0002-3967-2483 | |
| dc.identifier.orcid | https://orcid.org/0000-0003-3875-4775 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
