Investigating the Dearomative Rearrangement of Biaryl Phosphine-Ligated Pd(II) Complexes

Author(s)
Maimone, Thomas; Su, Mingjuan; Chen, Jiahao; Milner, Phillip John; Mueller, Peter; ... Show more
Thumbnail
DownloadBuchwald_Investigating the.pdf (6.827Mb)
PUBLISHER_POLICY
Terms of use
Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
Metadata
Show full item record
Abstract
A series of monoligated L·Pd[superscript II](Ar)X complexes (L = dialkyl biaryl phosphine) have been prepared and studied in an effort to better understand an unusual dearomative rearrangement previously documented in these systems. Experimental and theoretical evidence suggest a concerted process involving the unprecedented Pd[superscript II]-mediated insertion of an aryl group into an unactivated arene.
Date issued
2012-11
URI
http://hdl.handle.net/1721.1/93920
Department
Massachusetts Institute of Technology. Computer Science and Artificial Intelligence Laboratory; Massachusetts Institute of Technology. Department of Chemistry
Journal
Journal of the American Chemical Society
Publisher
American Chemical Society (ACS)
Citation
Milner, Phillip J., Thomas J. Maimone, Mingjuan Su, Jiahao Chen, Peter Müller, and Stephen L. Buchwald. “Investigating the Dearomative Rearrangement of Biaryl Phosphine-Ligated Pd(II) Complexes.” Journal of the American Chemical Society 134, no. 48 (December 5, 2012): 19922–19934.
Version: Author's final manuscript
ISSN
0002-7863
1520-5126
Collections