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Investigating the Dearomative Rearrangement of Biaryl Phosphine-Ligated Pd(II) Complexes

dc.contributor.authorMaimone, Thomas
dc.contributor.authorSu, Mingjuan
dc.contributor.authorChen, Jiahao
dc.contributor.authorMilner, Phillip John
dc.contributor.authorMueller, Peter
dc.contributor.authorBuchwald, Stephen Leffler
dc.date.accessioned2015-02-06T20:26:50Z
dc.date.available2015-02-06T20:26:50Z
dc.date.issued2012-11
dc.date.submitted2012-10
dc.identifier.issn0002-7863
dc.identifier.issn1520-5126
dc.identifier.urihttp://hdl.handle.net/1721.1/93920
dc.description.abstractA series of monoligated L·Pd[superscript II](Ar)X complexes (L = dialkyl biaryl phosphine) have been prepared and studied in an effort to better understand an unusual dearomative rearrangement previously documented in these systems. Experimental and theoretical evidence suggest a concerted process involving the unprecedented Pd[superscript II]-mediated insertion of an aryl group into an unactivated arene.en_US
dc.description.sponsorshipNational Institutes of Health (U.S.) (GM46059)en_US
dc.description.sponsorshipNational Institutes of Health (U.S.) (Postdoctoral Fellowship 1F32GM088931)en_US
dc.description.sponsorshipNational Science Foundation (U.S.) (Pre-doctoral Fellowship 2010094243)en_US
dc.description.sponsorshipAmgen Inc.en_US
dc.language.isoen_US
dc.publisherAmerican Chemical Society (ACS)en_US
dc.relation.isversionofhttp://dx.doi.org/10.1021/ja310351een_US
dc.rightsArticle is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.en_US
dc.sourcePMCen_US
dc.titleInvestigating the Dearomative Rearrangement of Biaryl Phosphine-Ligated Pd(II) Complexesen_US
dc.typeArticleen_US
dc.identifier.citationMilner, Phillip J., Thomas J. Maimone, Mingjuan Su, Jiahao Chen, Peter Müller, and Stephen L. Buchwald. “Investigating the Dearomative Rearrangement of Biaryl Phosphine-Ligated Pd(II) Complexes.” Journal of the American Chemical Society 134, no. 48 (December 5, 2012): 19922–19934.en_US
dc.contributor.departmentMassachusetts Institute of Technology. Computer Science and Artificial Intelligence Laboratoryen_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Chemistryen_US
dc.contributor.mitauthorMilner, Phillip Johnen_US
dc.contributor.mitauthorMaimone, Thomasen_US
dc.contributor.mitauthorSu, Mingjuanen_US
dc.contributor.mitauthorChen, Jiahaoen_US
dc.contributor.mitauthorMueller, Peteren_US
dc.contributor.mitauthorBuchwald, Stephen Leffleren_US
dc.relation.journalJournal of the American Chemical Societyen_US
dc.eprint.versionAuthor's final manuscripten_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/PeerRevieweden_US
dspace.orderedauthorsMilner, Phillip J.; Maimone, Thomas J.; Su, Mingjuan; Chen, Jiahao; Müller, Peter; Buchwald, Stephen L.en_US
dc.identifier.orcidhttps://orcid.org/0000-0003-3875-4775
dspace.mitauthor.errortrue
mit.licensePUBLISHER_POLICYen_US
mit.metadata.statusComplete


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