| dc.contributor.author | Kiesewetter, Matthew K. | |
| dc.contributor.author | Michaelis, Vladimir K. | |
| dc.contributor.author | Walish, Joseph John | |
| dc.contributor.author | Griffin, Robert Guy | |
| dc.contributor.author | Swager, Timothy M | |
| dc.date.accessioned | 2015-02-18T20:31:15Z | |
| dc.date.available | 2015-02-18T20:31:15Z | |
| dc.date.issued | 2014-02 | |
| dc.date.submitted | 2014-01 | |
| dc.identifier.issn | 1520-6106 | |
| dc.identifier.issn | 1520-5207 | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/94614 | |
| dc.description.abstract | We illustrate the ability to place a water-insoluble biradical, bTbk, into a glycerol/water matrix with the assistance of a surfactant, sodium octyl sulfate (SOS). This surfactant approach enables a previously water insoluble biradical, bTbk, with favorable electron–electron dipolar coupling to be used for dynamic nuclear polarization (DNP) nuclear magnetic resonance (NMR) experiments in frozen, glassy, aqueous media. Nuclear Overhauser enhancement (NOE) and paramagnetic relaxation enhancement (PRE) experiments are conducted to determine the distribution of urea and several biradicals within the SOS macromolecular assembly. We also demonstrate that SOS assemblies are an effective approach by which mixed biradicals are created through an assembly process. | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (Grant EB-002804) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (Grant EB-002026) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (Grant EB-001960) | en_US |
| dc.description.sponsorship | National Institutes of Health (U.S.) (Grant GM-095843) | en_US |
| dc.description.sponsorship | Natural Sciences and Engineering Research Council of Canada (Postdoctoral Fellowship) | en_US |
| dc.description.sponsorship | National Institutes of Health. National Institute for Biomedical Imaging and Bioengineering (Ruth L. Kirschstein National Research Service Award F32EB012937) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/jp410387e | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | PMC | en_US |
| dc.title | High Field Dynamic Nuclear Polarization NMR with Surfactant Sheltered Biradicals | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Kiesewetter, Matthew K., Vladimir K. Michaelis, Joseph J. Walish, Robert G. Griffin, and Timothy M. Swager. “High Field Dynamic Nuclear Polarization NMR with Surfactant Sheltered Biradicals.” The Journal of Physical Chemistry B 118, no. 7 (February 20, 2014): 1825–1830. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.department | Francis Bitter Magnet Laboratory (Massachusetts Institute of Technology) | en_US |
| dc.contributor.mitauthor | Kiesewetter, Matthew K. | en_US |
| dc.contributor.mitauthor | Michaelis, Vladimir K. | en_US |
| dc.contributor.mitauthor | Walish, Joseph John | en_US |
| dc.contributor.mitauthor | Griffin, Robert Guy | en_US |
| dc.contributor.mitauthor | Swager, Timothy Manning | en_US |
| dc.relation.journal | Journal of Physical Chemistry B | en_US |
| dc.eprint.version | Final published version | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Kiesewetter, Matthew K.; Michaelis, Vladimir K.; Walish, Joseph J.; Griffin, Robert G.; Swager, Timothy M. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0003-1589-832X | |
| dc.identifier.orcid | https://orcid.org/0000-0002-6708-7660 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
