Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products

Author(s)
Majumdar, Amit; Lippard, Stephen J.
Thumbnail
DownloadLippard_Non-heme.pdf (781.1Kb)
PUBLISHER_POLICY
Terms of use
Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use.
Metadata
Show full item record
Abstract
Mononitrosyldiiron complexes having either an [Fe[superscript II]·{FeNO}[superscript 7]] or an [Fe[superscript III]·{FeNO}[superscript 7]] core formulation have been synthesized by methods that rely on redox-state-induced differentiation of the diiron starting materials in an otherwise symmetrical dinucleating ligand environment. The synthesis, X-ray structures, Mössbauer spectroscopy, cyclic voltammetry, and dioxygen reactivity of [Fe[superscript III]·{FeNO}[superscript 7]] are described.
Date issued
2013-11
URI
http://hdl.handle.net/1721.1/95479
Department
Massachusetts Institute of Technology. Department of Chemistry
Journal
Inorganic Chemistry
Publisher
American Chemical Society (ACS)
Citation
Majumdar, Amit, and Stephen J. Lippard. “Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products.” Inorg. Chem. 52, no. 23 (December 2, 2013): 13292–13294.
Version: Author's final manuscript
ISSN
0020-1669
1520-510X
Collections