Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products
Author(s)
Majumdar, Amit; Lippard, Stephen J.
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Mononitrosyldiiron complexes having either an [Fe[superscript II]·{FeNO}[superscript 7]] or an [Fe[superscript III]·{FeNO}[superscript 7]] core formulation have been synthesized by methods that rely on redox-state-induced differentiation of the diiron starting materials in an otherwise symmetrical dinucleating ligand environment. The synthesis, X-ray structures, Mössbauer spectroscopy, cyclic voltammetry, and dioxygen reactivity of [Fe[superscript III]·{FeNO}[superscript 7]] are described.
Date issued
2013-11Department
Massachusetts Institute of Technology. Department of ChemistryJournal
Inorganic Chemistry
Publisher
American Chemical Society (ACS)
Citation
Majumdar, Amit, and Stephen J. Lippard. “Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products.” Inorg. Chem. 52, no. 23 (December 2, 2013): 13292–13294.
Version: Author's final manuscript
ISSN
0020-1669
1520-510X