| dc.contributor.author | Majumdar, Amit | |
| dc.contributor.author | Lippard, Stephen J. | |
| dc.date.accessioned | 2015-02-24T16:01:32Z | |
| dc.date.available | 2015-02-24T16:01:32Z | |
| dc.date.issued | 2013-11 | |
| dc.date.submitted | 2013-07 | |
| dc.identifier.issn | 0020-1669 | |
| dc.identifier.issn | 1520-510X | |
| dc.identifier.uri | http://hdl.handle.net/1721.1/95479 | |
| dc.description.abstract | Mononitrosyldiiron complexes having either an [Fe[superscript II]·{FeNO}[superscript 7]] or an [Fe[superscript III]·{FeNO}[superscript 7]] core formulation have been synthesized by methods that rely on redox-state-induced differentiation of the diiron starting materials in an otherwise symmetrical dinucleating ligand environment. The synthesis, X-ray structures, Mössbauer spectroscopy, cyclic voltammetry, and dioxygen reactivity of [Fe[superscript III]·{FeNO}[superscript 7]] are described. | en_US |
| dc.description.sponsorship | National Institute of General Medical Sciences (U.S.) (Grant GM 32114) | en_US |
| dc.language.iso | en_US | |
| dc.publisher | American Chemical Society (ACS) | en_US |
| dc.relation.isversionof | http://dx.doi.org/10.1021/ic4019508 | en_US |
| dc.rights | Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. | en_US |
| dc.source | PMC | en_US |
| dc.title | Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products | en_US |
| dc.type | Article | en_US |
| dc.identifier.citation | Majumdar, Amit, and Stephen J. Lippard. “Non-Heme Mononitrosyldiiron Complexes: Importance of Iron Oxidation State in Controlling the Nature of the Nitrosylated Products.” Inorg. Chem. 52, no. 23 (December 2, 2013): 13292–13294. | en_US |
| dc.contributor.department | Massachusetts Institute of Technology. Department of Chemistry | en_US |
| dc.contributor.mitauthor | Lippard, Stephen J. | en_US |
| dc.contributor.mitauthor | Majumdar, Amit | en_US |
| dc.relation.journal | Inorganic Chemistry | en_US |
| dc.eprint.version | Author's final manuscript | en_US |
| dc.type.uri | http://purl.org/eprint/type/JournalArticle | en_US |
| eprint.status | http://purl.org/eprint/status/PeerReviewed | en_US |
| dspace.orderedauthors | Majumdar, Amit; Lippard, Stephen J. | en_US |
| dc.identifier.orcid | https://orcid.org/0000-0002-2693-4982 | |
| mit.license | PUBLISHER_POLICY | en_US |
| mit.metadata.status | Complete | |
