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Strategic use of nickel(0)-catalyzed enyne–epoxide reductive coupling toward the synthesis of (−)-cyatha-3,12-diene

dc.contributor.authorSparling, Brian A.
dc.contributor.authorSimpson, Graham L.
dc.contributor.authorJamison, Timothy F.
dc.date.accessioned2015-10-29T17:49:40Z
dc.date.available2015-10-29T17:49:40Z
dc.date.issued2008-11
dc.date.submitted2008-11
dc.identifier.issn00404020
dc.identifier.urihttp://hdl.handle.net/1721.1/99513
dc.description.abstractVarious situations are explored in which the nickel(0)-catalyzed enyne–epoxide reductive coupling was utilized to access key intermediates toward the total synthesis of (−)-cyatha-3,12-diene (1). Enantioenriched 3,5-dien-1-ols with a variety of functionality were obtained in a straightforward manner from easily accessible 1,3-enynes and terminal epoxides.en_US
dc.description.sponsorshipNational Institute of General Medical Sciences (U.S.) (GM-063755)en_US
dc.description.sponsorshipMassachusetts Institute of Technology. Undergraduate Research Opportunities Programen_US
dc.language.isoen_US
dc.publisherElsevieren_US
dc.relation.isversionofhttp://dx.doi.org/10.1016/j.tet.2008.11.086en_US
dc.rightsCreative Commons Attribution-Noncommercial-NoDerivativesen_US
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/en_US
dc.sourcePMCen_US
dc.titleStrategic use of nickel(0)-catalyzed enyne–epoxide reductive coupling toward the synthesis of (−)-cyatha-3,12-dieneen_US
dc.typeArticleen_US
dc.identifier.citationSparling, Brian A., Graham L. Simpson, and Timothy F. Jamison. “Strategic Use of Nickel(0)-Catalyzed Enyne–epoxide Reductive Coupling Toward the Synthesis of (−)-Cyatha-3,12-Diene.” Tetrahedron 65, no. 16 (April 2009): 3270–3280.en_US
dc.contributor.departmentMassachusetts Institute of Technology. Department of Chemistryen_US
dc.contributor.mitauthorSparling, Brian A.en_US
dc.contributor.mitauthorSimpson, Graham L.en_US
dc.contributor.mitauthorJamison, Timothy F.en_US
dc.relation.journalTetrahedronen_US
dc.eprint.versionAuthor's final manuscripten_US
dc.type.urihttp://purl.org/eprint/type/JournalArticleen_US
eprint.statushttp://purl.org/eprint/status/PeerRevieweden_US
dspace.orderedauthorsSparling, Brian A.; Simpson, Graham L.; Jamison, Timothy F.en_US
dc.identifier.orcidhttps://orcid.org/0000-0002-8601-7799
mit.licensePUBLISHER_CCen_US
mit.metadata.statusComplete


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